Ink can be a complex medium, composed of
solvents, pigments, dyes,
resins,
lubricants,
solubilizers,
surfactants,
particulate matter,
fluorescents, and other materials. The components of inks serve many purposes; the ink’s carrier, colorants, and other additives affect the flow and thickness of the ink and its dry appearance.
History
Many ancient cultures around the world have independently discovered and formulated inks for the purposes of writing and drawing. The knowledge of the inks, their recipes and the techniques for their production comes from archaeological analysis or from written text itself.
The history of Chinese inks can be traced back to the 23rd century BC, with the utilization of natural plant (plant dyes), animal, and mineral inks based on such materials as
graphite that were ground with water and applied with
ink brushes. Evidence for the earliest Chinese inks, similar to modern
inksticks, is around 256 BC in the end of the
Warring States period and produced from
soot and
animal glue.
The best inks for drawing or painting on paper or silk are produced from the resin of the pine tree. They must be between 50 and 100 years old. The Chinese inkstick is produced with a fish glue, whereas Japanese glue (膠 "nikawa") is from cow or stag.
The process of making
India ink was known in China as early as the middle of the 3rd millennium BC, during
Neolithic China.
[7] India ink was first invented in China, although the source of materials to make the carbon pigment in India ink was later often traded from India, thus the term
India ink was coined. The traditional Chinese method of making the ink was to grind a mixture of
hide glue,
carbon black, lampblack, and
bone black pigment with a
pestle and mortar, then pouring it into a ceramic dish where it could dry. To use the dry mixture, a wet brush would be applied until it reliquified. The manufacture of India ink was well-established by the
Cao Wei Dynasty (220–265 AD). Indian documents written in
Kharosthi with ink have been unearthed in
Chinese Turkestan.The practice of writing with ink and a sharp pointed needle was common in early
South India. Several
Buddhist and
Jain sutras in India were compiled in ink.
About 1,600 years ago, a popular ink recipe was created. The recipe was used for centuries. Iron salts, such as ferrous sulfate (made by treating iron with sulfuric acid), were mixed with tannin from
gallnuts (they grow on trees) and a thickener. When first put to paper, this ink is bluish-black. Over time it fades to a dull brown.
Scribes in
medieval Europe (about AD 800 to 1500) wrote principally on
parchment or
vellum. One 12th century ink recipe called for hawthorn branches to be cut in the spring and left to dry. Then the bark was pounded from the branches and soaked in water for eight days. The water was boiled until it thickened and turned black. Wine was added during boiling. The ink was poured into special bags and hung in the sun. Once dried, the mixture was mixed with wine and iron salt over a fire to make the final ink.
The reservoir pen, which may have been the first
fountain pen, dates back to 953, when
Ma'ād al-Mu'izz, the
caliph of
Egypt, demanded a pen that would not stain his hands or clothes, and was provided with a pen that held ink in a reservoir.
In the 15th century, a new type of ink had to be developed in Europe for the
printing press by
Johannes Gutenberg. According to Martyn Lyons in his book
Books: A Living History, Gutenberg’s dye was indelible, oil-based, and made from the soot of lamps (lamp-black) mixed with varnish and egg white. Two types of ink were prevalent at the time: the Greek and Roman writing ink (soot, glue, and water) and the 12th century variety composed of ferrous sulfate, gall, gum, and water.
[Neither of these handwriting inks could adhere to printing surfaces without creating blurs. Eventually an oily, varnish-like ink made of soot,
turpentine, and walnut oil was created specifically for the printing press.
In 2011 worldwide consumption of printing inks generated revenues of more than 20 billion US dollars. Demand by traditional print media is shrinking, on the other hand more and more printing inks are consumed for packagings.